13 April 2015

The curves of thermal radiation

Thermal radiation is another name for blackbody radiation.  Both terms refer to the emission of light and other non-ionizing radiation from a heated object based solely on the object's temperature.  So sometimes it's also called "temperature radiation."  Also, we're not concerned with the perfect blackbody here, except as a standard for comparision.

So, how else does light get produced other than the heat-it-till-it-glows method? Well, there's fluorescence,  the process that goes on inside a fluorescent bulb, where ultraviolet radiation is absorbed by an atom and visible light is emitted. Fluorescent lights use high voltage to stimulate mercury atoms to emit ultraviolet photons which hit the visible-light emitting phosphor coating on the inside of the tube.  (A related, delayed type of light emission is called phosphorescence.)  LEDs emit light by electroluminescence, where the "bandgap" energy in a semiconductor connected to a DC voltage is turned into light. And then there's the chemiluminescence of fireflies and green-light glow-in-the-dark thingies, but you can click the link to read about that.

For thermal radiation to be visible, the heated body must be hot enough to produce light in the visible spectrum (390 to 700 nanometers, violet wavelength to red wavelength).  Incandescent light bulbs are one example of that, producing light by being heated by an electric current to temperatures around 4500° F.  Stars, including our Sun, are also examples, with surface temperatures in the range of  10,000° F.  But thermal radiation is emitted by any object that's not at absolute zero of temperature--so all objects emit thermal radiation, mostly at very long wavelengths. The Earth, for instance, emits thermal radiation in the infrared region of the electromagnetic spectrum , which goes from 750 nanometers on up to about a million nanometers, or one millimeter. This emission is due to Earth's own internal heat, and from light it absorbs from the sun and re-emits as heat. Our bodies also emit thermal radiation in the infrared region. Our average power output is about 100 watts, another way of saying 2,065 Calories/day.  We are visible not because of radiation we emit but because, like the things around us, we reflect most of the visible light hitting us. This is called diffuse reflection rather than mirror-type (specular) reflection.

The hotter an object is, the shorter the wavelengths of light emitted by the object. (Shorter wavelength means higher frequency.) The webpage I just linked to shows the blackbody curves (spectra) of energy emitted versus wavelength. Optical pyrometers use this spectral relationship--the relationship Max Planck explained by assuming quantized emission of thermal radiation--to measure the temperatures of hot objects such as molten steel.

An aside: Lighting techniques in stage lighting and photography make use of something called "color temperature," which uses the idea of thermal or blackbody radiation as a reference standard, although it associates "warm" colors with what are actually cool objects and "cool" colors with what are actually hot objects.